25 Celebrity Couples You Forgot Were Once Married

3. George Clooney and Talia Balsam

George Clooney and Talia Balsam-people.com

Long before George Clooney tied the knot with Amal, he was married to Talia Balsam. We have no idea how Talia managed to coerce and lure George into marrying her. She is not exactly a household name. She was also once married to her Mad Men co-star, John Slattery.

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